Solar Photo-Fenton Induced Degradation of Combined Chlorpyrifos, Cypermethrin and Chlorothalonil Pesticides in Aqueous Solution

The feasibility of employing solar radiation for
enhanced Fenton process in degradation of combined chlorpyrifos,
cypermethrin and chlorothalonil pesticides was examined. The effect
of various operating conditions of the process on biodegradability
improvement and mineralization of the pesticides were also
evaluated. The optimum operating conditions for treatment of
aqueous solution containing 100, 50 and 250 mg L-1 chlorpyrifos
cypermethrin and chlorothalonil, respectively were observed to be
H2O2/COD molar ratio 2, H2O2/Fe2+ molar ratio 25 and pH 3. Under
the optimum operating conditions, complete degradation of the
pesticides occurred in 1 min. Biodegradability (BOD5/COD)
increased from zero to 0.36 in 60 min, and COD and TOC removal
were 74.19 and 58.32%, respectively in 60 min. Due to
mineralization of organic carbon, decrease in ammonia-nitrogen from
22 to 4.3 mg L-1 and increase in nitrate from 0.7 to 18.1 mg L-1 in
60 min were recorded. The study indicated that solar photo-Fenton
process can be used for pretreatment of chlorpyrifos, cypermethrin
and chlorothalonil pesticides in aqueous solution for further
biological treatment.