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Thermophysical properties of 1-alkylpyridinum bis(trifluoromethylsulfonyl)imide ionic liquids

M. Yunus, Normawati and Abdul Mutalib, M I and Man, Zakaria and Bustam, Mohamad Azmi and Murugesan, Thanapalan (2010) Thermophysical properties of 1-alkylpyridinum bis(trifluoromethylsulfonyl)imide ionic liquids. J. Chem. Thermodynamics , 42 (4). pp. 491-495. ISSN 0021-9614

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Official URL: http://www.elsevier.com/wps/find/journaldescriptio...

Abstract

The thermophysical properties of 1-alkylpyridinium bis(trifluoromethylsulfonyl)imide, [Cnpy][Tf2N] ionic liquids where n = 4, 8, 10, or 12 have been determined. Density q, and dynamic viscosity g, were determined at T = (293.15 to 353.15) K and refractive index nD, was measured at T = (293.15 to 333.15) K. Empirical correlations are proposed to represent the present experimental results. The values of the coefficient of thermal expansion were calculated from the experimental density values. The thermal decomposition temperature, Td was also determined using thermogravimetric analyzer (TGA) at a heating rate of (10 and 20) K min1.

Item Type:Article
Subjects:T Technology > T Technology (General)
Departments / MOR / COE:Departments > Chemical Engineering
ID Code:3445
Deposited By: Assoc Prof Dr Mohamad Azmi Bustam @ Khalil
Deposited On:23 Dec 2010 03:25
Last Modified:02 Apr 2014 00:47

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