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Tuning the gas separation performance of fluorinated and sulfonated PEEK membranes by incorporation of zeolite 4A

Tahir, Z. and Ilyas, A. and Li, X. and Bilad, M.R. and Vankelecom, I.F.J. and Khan, A.L. (2018) Tuning the gas separation performance of fluorinated and sulfonated PEEK membranes by incorporation of zeolite 4A. Journal of Applied Polymer Science, 135 (10).

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Abstract

Mixed matrix membranes (MMMs) containing fluorinated-sulfonated poly(ether ether ketone) (F-SPEEK) and zeolite 4A filler, were prepared by solution casting. F-SPEEK with a fixed degree of sulfonation (40) was used for membrane synthesis. The SEM pictures showed good interfacial adhesion between filler particles and polymer, which was also confirmed by the increase in glass transition temperature of MMMs with increase in filler particles. Pure and mixed gas permeation experiments were carried out to investigate the potential of this membrane material. The results revealed that addition of zeolite 4A fillers enhanced both permeability and selectivity owing to the intrinsic nature of polymer and modified membrane morphology due to filler. The highest permeability obtained for CO2 at 30 filler loading was 49.2 Barrer, while highest selectivities obtained for CO2/CH4 and CO2/N2 were 55 and 58 compared to 47 and 51 for the unfilled polymer, respectively. Intrinsic CO2 solubility of F-SPEEK was observed to be decreased from 10.7 to 1.9 (10�2) cm3 (STP)/cm3 cmHg with the addition of Zeolite 4A. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 45952. © 2017 Wiley Periodicals, Inc.

Item Type:Article
Impact Factor:cited By 2
Uncontrolled Keywords:Carbon dioxide; Ethers; Filled polymers; Fillers; Films; Glass transition; Ketones; Membranes; Polymers; Zeolites, Degree of sulfonation; Gas separation performance; Interfacial adhesions; Mixed gas permeation; Mixed matrix membranes; Modified membranes; Oil and gas; Sulfonated poly(ether ether ketone)s, Gas permeable membranes
Departments / MOR / COE:Research Institutes > Institute for Sustainable Building
ID Code:21712
Deposited By: Ahmad Suhairi
Deposited On:01 Aug 2018 02:08
Last Modified:07 Jan 2019 07:29

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