De-acidification of crude oil using supported ionic liquids phases

Shah, S.N. and Pranesh, M. and Raj, J.J. and Mutalib, M.I.A. and Lethesh, K.C. and Ghanem, O.B. and Ullah, Z. (2018) De-acidification of crude oil using supported ionic liquids phases. Separation and Purification Technology, 196. pp. 96-105.

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Abstract

In this study, imidazolium based ionic liquids with different functional group were chemically tethered to silica support and resulted in silica supported solid ionic liquids phases (SILPs). The SILPS were characterized using CHNS elemental analysis, Fourier Transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and thermo gravimetric analysis (TGA). The adsorption of commercial naphthenic acid from dodecane/kerosene was performed using SILPs. It was observed that their adsorption efficiency varied depending on the functional group on the imidazolium cation. This study was also modeled using COSMO-RS. The SILPs are efficient adsorbent in the extraction of naphthenic acid from highly acidic model oil. The recovery of adsorbed naphthenic acids from the SILPs was also investigated. © 2017 Elsevier B.V.

Item Type: Article
Impact Factor: cited By 0
Uncontrolled Keywords: Adsorption; Crude oil; Extraction; Fourier transform infrared spectroscopy; Gravimetric analysis; Liquids; Organic acids; Scanning electron microscopy; Silica; Thermogravimetric analysis, Adsorption efficiency; Dodecane; Imidazolium cation; Imidazolium-based ionic liquid; Ionic liquid (ils); Naphthenic acid; Silica supports; Supported ionic liquids, Ionic liquids
Depositing User: Mr Ahmad Suhairi Mohamed Lazim
Date Deposited: 26 Feb 2019 02:57
Last Modified: 26 Feb 2019 02:57
URI: http://scholars.utp.edu.my/id/eprint/20929

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